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Cyanide Ion Promoted Addition of Acylphosphonates to Diethyl Cyanophosphonate: Synthesis of Phosphonocyanohydrin O-Phosphates
Date
2009-05-18
Author
Demir, Ayhan Sıtkı
Aybey, Asuman
Emrullahoglu, Mustafa
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Cyanide ion catalyzed addition of acylphosphonates to diethyl cyanophosphonate furnished phosphonocyanohydrin O-phosphates in high yield. The reaction works via the phosphonate-phosphate rearrangement, followed by the addition of diethyl cyanophosphonate to the cyanohydrin phosphate anion.
Subject Keywords
Organic Chemistry
,
Catalysis
URI
https://hdl.handle.net/11511/62854
Journal
SYNTHESIS-STUTTGART
DOI
https://doi.org/10.1055/s-0029-1216634
Collections
Department of Chemistry, Article
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A. S. Demir, A. Aybey, and M. Emrullahoglu, “Cyanide Ion Promoted Addition of Acylphosphonates to Diethyl Cyanophosphonate: Synthesis of Phosphonocyanohydrin O-Phosphates,”
SYNTHESIS-STUTTGART
, pp. 1655–1658, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62854.